解永樹

解永樹，教授、博導，上海市東方學者特聘教授、教育部新世紀優秀人才。1971 年 10 月出生於安徽廬江。1998 年於浙江大學化學系獲博士學位，導師為林瑞森教授。同年到中國科技大學化學系劉清亮教授研究組從事博士後研究。

基本介紹

• 中文名：解永樹
• 出生日期：1971 年 10 月
• 出生地：安徽廬江
• 畢業院校：浙江大學
• 導師：林瑞森教授
• 職業：教授、博導
• 主要成就：上海市浦江人才 (2008)
•           ：教育部新世紀優秀人才 (2011)
•            ：上海市東方學者特聘教授（2011）

人物經歷

解永樹，教授、博導，上海市東方學者特聘教授、教育部新世紀優秀人才。1971 年 10 月出生於安徽廬江。1998 年於浙江大學化學系獲博士學位，導師為林瑞森教授。同年到中國科技大學化學系劉清亮教授研究組從事博士後研究。2000 年 7 月留校任副教授。2003 年至 2007 年間，先後到台灣大學彭旭明教授研究組，日本九州大學 Furuta Hiroyuki 教授研究組以及日本國立材料研究所 Ariga Katsuhiko 與J. P. Hill 教授研究組作訪問研究。2007 年 8 月回國，被聘為華東理工大學化學與分子工程學院教授，現為精細合成化學與分子工程碩士點導師組組長。

研究方向

1、精細有機合成：設計、合成新型有機光電功能分子，套用於螢光探針和光電轉換等領域。

2、新型卟啉研究：基於“生命色素”卟啉，開展功能導向的新型卟啉研究，套用於太陽能電池等領域。

主要成就

獲得榮譽

2008年 上海市浦江人才

2011年 教育部新世紀優秀人才

2011年 上海市東方學者特聘教授

2014年 中國化學會卟啉與酞菁專業委員會副主任委員

研究成果

圍繞卟啉這一自然界廣泛存在的重要功能分子，系統開展特殊功能導向的新型卟啉共軛結構設計、合成與功能調控研究。通過卟啉染料結構最佳化與共敏化策略，將染料敏化太陽能電池效率從母體結構的 2.2% 大幅提高至 11.5%，取得基於碘電解質的非釕染料敏化電池的最高光電轉換效率。同時，還系統開展了螢光探針研究，套用於生物體和環境領域有重要價值的離子的檢測。發表 SCI 論文 140 余篇，其中 Angew. Chem. Int. Ed. 10 篇， J. Am. Chem. Soc. 3 篇，並應邀發表 Chem. Rev. 和 Chem. Soc. Rev. 綜述各 1 篇。全部論文 SCI 他引 2300 余次。兩次被 Angew. Chem. Int. Ed. highlight 專題報導。申請國際發明專利 2 項，已授權 1 項。目前負責國家自然科學基金面上項目、國家自然科學基金重大研究計畫子課題等項目。

近年來發表的代表性學術論文

1) Yubin Ding, Wei-Hong Zhu, and Yongshu Xie*, Development of ion sensors based on porphyrin analogues, Chem. Rev.,DOI: 10.1021/acs.chemrev.6b00021 (IF 46.568).

2) Yubin Ding, Yunyu Tang, Weihong Zhu, and Yongshu Xie*, Fluorescent and colorimetric ion probes based on conjugated oligopyrroles, Chem. Soc. Rev., 2015, 44, 1101–1112 (IF 33.383).

3) Miao Li, Pingchun Wei, Masatoshi Ishida, Xin Li, Mathew Savage, Rui Guo, Zhongping Ou, Sihai Yang, Hiroyuki Furuta,* and Yongshu Xie*, Macrocyclic transformations from norrole to isonorrole and an N-confused corrole with a fused hexacyclic ring triggered by a pyrrole substituent, Angew. Chem. Int. Ed., 2016, 55, 3063 (IF 11.261).

4) Yongshu Xie*, Yunyu Tang, Wenjun Wu, Yueqiang Wang, Jingchuan Liu, Xin Li, He Tian, and Wei-Hong Zhu*, Porphyrin cosensitization for a photovoltaic efficiency of 11.5%: a record for non-ruthenium solar cells based on iodine electrolyte, J. Am. Chem. Soc., 2015, 137, 14055–14058 (IF 12.113).

5) Andong Shao, Yongshu Xie, Shaojia Zhu, Zhiqian Guo,* Shiqin Zhu, Jin Guo, Ping Shi, Tony D. James, He Tian, and Wei-Hong Zhu*, Far-red and near-IR AIE-active fluorescent organic nanoprobes with enhanced tumor-targeting efficacy: shape-specific effects, Angew. Chem. Int. Ed., 2015, 54(25), 7275-7280 (IF 11.261).

6) Yueqiang Wang, Bin Chen, Wenjun Wu, Xin Li, Weihong Zhu, He Tian andYongshu Xie*, Efficient solar cells sensitized by porphyrins with an extended conjugation framework and a carbazole donor: from molecular design to cosensitization, Angew. Chem. Int. Ed., 2014, 53, 10779–10783 (IF 11.261).

7) Pingchun Wei, Kai Zhang, Xin Li, Deying Meng, Hans Ågren, Zhongping Ou, Seikweng Ng, Hiroyuki Furuta*, and Yongshu Xie*, Neo-fused hexaphyrin: a molecular puzzle containing an N-linked pentaphyrin, Angew. Chem. Int. Ed., 2014, 53, 14069–14073 (IF 11.261).

8) Yue Wu, Yongshu Xie, Qiong Zhang, He Tian, Weihong Zhu*, Alexander D. Q. Li*, Quantitative photoswitching in bis(dithiazole)ethene enables modulation of light for encoding optical signals, Angew. Chem., Int. Ed., 2014, 53, 2090–2094 (IF 11.261).

9) Wenlong Li, Changhong Jiao, Xin Li, Yongshu Xie, Keitaro Nakatani, He Tian, Weihong Zhu, Separation of photoactive conformers based on hindered diarylethenes: efficient modulation in photocyclization quantum yields, Angew. Chem. Int. Ed., 2014, 53, 4603–4607 (IF 11.261).

10) Yongshu Xie*, Pingchun Wei, Xin Li, Tao Hong, Kai Zhang, and Hiroyuki Furuta*, Macrocycle contraction and expansion of a dihydrosapphyrin isomer, J. Am. Chem. Soc., 2013, 135, 19119–19122 (IF 12.113).

11) Zhiyun Zhang, Bo Xu, Jianhua Su, Leiping Shen, Yongshu Xie, He Tian*, Color-tunable solid-state emission of 2,2'-biindenyl-based fluorophores, Angew. Chem. Int. Ed., 2011, 50, 11654–11657 (IF 11.261).

12) Weihong Zhu*, Yuheng Yang, Rémi Métivier, Qiong Zhang, Régis Guillot, Yongshu Xie, He Tian, Keitaro Nakatani*, Unprecedented stability of a photochromic bisthienylethene based on benzobisthiadiazole as an ethene bridge, Angew. Chem. Int. Ed. 2011, 50, 10986–10990 (IF 11.261).

13) Yongshu Xie, Keisuke Yamaguchi, Motoki Toganoh, Hidemitsu Uno, Masaaki Suzuki, Shigeki Mori, Shohei Saito, Atsuhiro Osuka*, Hiroyuki Furuta*, Triply N-confused hexaphyrins: near-infrared luminescent dyes with a triangular shape, Angew. Chem. Int. Ed., 2009, 48, 5496–5499 (IF 11.261).

14) Francis D’Souza*, Navaneetha K. Subbaiyan, Yongshu Xie, Jonathan P. Hill*, Katsuhiko Ariga, Kei Ohkubo, and Shunichi Fukuzumi*, Anion-complexation-induced stabilization of charge separation, J. Am. Chem. Soc., 2009, 131, 16138–16146 (IF 12.113).

15) Yongshu Xie, Tatsuki Morimoto, Hiroyuki Furuta*,Sn complexes of N-confused porphyrins and oxoporphyrins - Unique fluorescence "Switch-On" halide receptors, Angew. Chem. Int. Ed., 2006, 45, 6907–6910 (IF 11.261).

16) Yongshu Xie, Wenjun Wu, Haibo Zhu, Jingchuan Liu, Weiwei Zhang, He Tian, and Wei-Hong Zhu*, Unprecedentedly targeted customization of molecular energy levels with auxiliary-groups in organic solar cell sensitizers, Chem. Sci., 2016, 7, 544-549 (IF 9.211).

17) Kai Zhang, Mathew Savage, Xin Li, Yu Jiang, Masatoshi Ishida, Koki Mitsuno, Satoru Karasawa, Tatsuhisa Kato, Weihua Zhu, Sihai Yang, Hiroyuki Furuta, and Yongshu Xie*, Rational syntheses of helical π-conjugated oligopyrrins with a bipyrrole linkage: geometry control of bis-copper(II) coordination, Chem. Commun.,2016, DOI: 10.1039/C6CC00707D (IF 6.834).

18) Yunyu Tang, Yueqiang Wang, Xin Li, Hans Ågren, Wei-Hong Zhu, and Yongshu Xie*, Porphyrins containing a triphenylamine donor and up to eight alkoxy chains for dye-sensitized solar cells: a high efficiency of 10.9%, ACS Appl. Mater. Interf., 2015, 7(50), 27976-27985 (IF 6.723).

19) Hai-Tao Feng, Jia-Bin Xiong, Yan-Song Zheng,*, Biao Pan, Chun Zhang,*, Lei Wang, and Yongshu Xie, Multicolor emissions by the synergism of intra/intermolecular slipped π-π stackings of tetraphenylethylene-DiBODIPY conjugate, Chem. Mater., 2015, 27(22), 7812-7819 (IF 8.354).

20) Jingchuan Liu, Bo Liu, Yunyu Tang, Weiwei Zhang, Wenjun Wu, Yongshu Xie and Wei-Hong Zhu*, Highly efficient cosensitization of D–A–p–A benzotriazole organic dyes with porphyrin for panchromatic dye-sensitized solar cells, J. Mater. Chem. C, 2015, 3, 11144-11150 (IF 4.696).

21) Wei Tiantian, Xi Sun, Xin Li,* Hans Ågren, and Yongshu Xie*, Systematic investigations on the roles of the electron acceptor and neighboring ethynylene moiety in porphyrins for dye-sensitized solar cells, ACS Appl. Mater. Interf., 2015, 7, 21956−21965 (IF 6.723).

22) Kai Zhang, Junda Zhang, Xin Li, Rui Guo, Hans Ågren, Zhongping Ou, Masatoshi Ishida, Hiroyuki Furuta,* and Yongshu Xie*, Synthesis of a neo-confused octaphyrin and the formation of its mononuclear complexes, Org. Lett. 2015, 17, 4806−4809 (IF 6.364).

23) Xueli Shen, Xiaodong Wei, Pengli Tan,Yingguo Yu, Biao Yang, Zhongmiao Gong, Haiming Zhang, Haiping Lin, Youyong Li, Qing Li,* Yongshu Xie,* Lifeng Chi,* Concentration-controlled reversible phase transitions in self-assembled monolayers on HOPG surfaces, Small, 2015, 11(19), 2284-2290 (IF 8.368).

24) Wenlong Li, Xin Li, Yongshu Xie, Yue Wu, Mengqi Li, Xin-Yan Wu, Wei-Hong Zhu,* He Tian, Enantiospecific photoresponse of sterically hindered diarylethenes for chiroptical switches and photomemories, Scientific Reports, 2015, srep09186 (IF 5.578).

25) Yunyu Tang, Yubin Ding, Xin Li, Hans Ågren, Tong Li, Weibing Zhang, Yongshu Xie*, Acylation of dipyrromethanes at the a and b positions and further development of fluorescent Zn probes, Sensors and Actuators B: Chemical, 2015, 206, 291–302 (IF 4.097).

26) Kai Zhang, Pingchun Wei, Xin Li, Hans Ågren, Yongshu Xie*, Oxidative ring closure and metal triggered ring opening: syntheses of macrocyclic and linear hexapyrroles, Org. Lett., 2014, 16, 6354–6357 (IF 6.364).

27) Xi Sun, Yueqiang Wang, Xin Li, Hans Ågren, Weihong Zhu, He Tian, and Yongshu Xie*, Cosensitizers for simultaneous filling up both absorption valleys of porphyrins: a novel approach for developing efficient panchromatic dye-sensitized solar cells, Chem. Commun., 2014, 50, 15609–15612 (IF 6.834).

28) Yubin Ding, Xin Li, Jonathan P. Hill, Katsuhiko Ariga, Hans Ågren, Joakim Andréasson, Weihong Zhu, He Tian, Yongshu Xie*, Acid/Base switching of the tautomerism and conformation of a dioxoporphyrin for integrated binary subtraction, Chem. Eur. J., 2014, 20, 12910–12916 (IF 5.731).

29) Caixia Ding, Xing Rui, Cheng Wang, Yongshu Xie*, Coordination polymers of a multipyridyl and pyrazolyl ligand with conformational flexibility: syntheses, structures and luminescence, CrystEngComm, 2014, 16, 1010–1019 (IF 4.034).

30) Bin Chen, Xi Sun, Xin Li, Hans Ågren,Yongshu Xie*, TICT based fluorescence “turn-on” hydrazine probes, Sensors and Actuators B: Chemical, 2014, 199, 93–100 (IF 4.097).

31) Quanzheng Zha, Xing Rui, Tiantian Wei and Yongshu Xie*, Recent advances in the design strategies for porphyrin-based coordination polymers, CrystEngComm, 2014, 16, 7371–7384 (IF 4.034).

32) Yue Wu, Weihong Zhu*, Wei Wan, Yongshu Xie, He Tian and Alexander D. Q. Li*, Reversible photoswitching specifically responds to mercury(II) ions: the gated photochromism of bis(dithiazole)ethene, Chem. Commun., 2014, 50, 14205–14208 (IF 6.834).

33) Bin Chen, Yubin Ding, Xin Li, Weihong Zhu, Jonathan P. Hill, Katsuhiko Ariga and Yongshu Xie,* Steric hindrance-enforced distortion as a general strategy for the design of fluorescence “turn-on” cyanide probes, Chem. Commun., 2013, 49, 10136–10138 (IF 6.834).

34) Bin Chen, Gang Yu, Xin Li, Yubin Ding, Cheng Wang, Zhiwei Liu*, and Yongshu Xie*, Full-colour luminescent compounds based on anthracene and 2,2′-dipyridylamine, J. Mater. Chem. C, 2013, 1, 7409–7417 (IF 4.696).

35) Quanzheng Zha, Caixia Ding, Xing Rui, Yongshu Xie*, A novel porphyrin based ligand containing four 4,4¢-dipyridylamine moieties ¾ syntheses, structures, and luminescent properties of Mn(II), Cu(II), Zn(II), and Cd(II) coordination polymers, Cryst. Growth Des., 2013, 13, 4583–4590 (IF 4.891).

36) Yubin Ding, Xin Li, Tong Li, Weihong Zhu, Yongshu Xie*, α-Monoacylated, α,α¢- and α,β¢- diacylated dipyrrins as highly sensitive fluorescence “turn-on” Zn probes, J. Org. Chem., 2013, 78, 5328−5338 (IF 4.721).

37) Caixia Ding, Chen Gao, Seikweng Ng, Bingwu Wang,* Yongshu Xie*, Polynuclear complexes with alkoxo and phenoxo bridges from in situ generated hydroxy-rich Schiff base ligands: syntheses, structures and magnetic properties, Chem. Eur. J., 2013, 19, 9961–9972 (IF 5.731).

38) Farkhondeh Fathi, Cong Kong, Yueqiang Wang, Yongshu Xie, Yi-Tao Long*, and Heinz-Bernhard Kraatz*, Tailoring zinc porphyrin to the Ag nanostructure substrate: an effective approach for photoelectrochemical studies in the presence of mononucleotides, Analyst, 2013, 138, 3380–3387 (IF 4.107).

39) Jonathan P. Hill*, Yongshu Xie, Misaho Akada, Yutaka Wakayama, Lok Kumar Shrestha, Qingmin Ji, Katsuhiko Ariga, Controlling porphyrin nanoarchitectures at solid interfaces, Langmuir, 2013, 29, 7291–7299 (IF 4.457).

40) Chuanxing Shi, Zhiqian Guo, Yongli Yan, Shiqin Zhu, Yongshu Xie, Yongsheng Zhao*, Weihong Zhu*, He Tian, Self-assembly solid-state enhanced red emission of quinolinemalononitrile: optical waveguides and stimuli response, ACS Appl. Mater. Interf. 2013, 5, 192–198 (IF 6.723).

41) Yongshu Xie,* Yubin Ding, Xin Li, Cheng Wang, Jonathan P. Hill*, Katsuhiko Ariga, Weibing Zhang, and Weihong Zhu, Selective, sensitive and reversible “turn-on” fluorescent cyanide probes based on 2,2’-dipyridylaminoanthracene-Cu ensembles, Chem. Commun., 2012, 48, 11513–11515 (IF 6.834).

42) Yuheng Yang, Yongshu Xie, Qiong Zhang, Keitaro Nakatani, He Tian, and Weihong Zhu*, Aromaticity-controlled thermal stability of photochromic systems based on a six-membered ring as ethene bridges: photochemical and kinetic studies, Chem. Eur. J., 2012, 18, 11685–11694 (IF 5.731).

43) Caixia Ding,Jia Ni, Yuhua Yang,Seik-weng Ng,Bingwu Wang, Yongshu Xie*, Mono-, tetra- and octanuclear transition metal complexes of in situ generated Schiff base ligands containing up to 12 coordinating atoms: syntheses, structures and magnetism, CrystEngComm, 2012, 14, 7312–7319 (IF 4.034).

44) Caixia Ding,Xing Li,Yubin Ding,Xin Li,Seik Weng Ng,Yongshu Xie*, A novel bis(4,4¢-dipyridylamine) ligand with a flexible butadiyne linker: syntheses, structures, and photoluminescence of d metal coordination polymers,Cryst. Growth Des., 2012, 12, 3465–3473 (IF 4.891).

45) Jonathan P. Hill*, Navaneetha K. Subbaiyan, Francis D’Souza*, Yongshu Xie*, Satyajit Sahu, Noelia M. Sanchez-Ballester, Gary J. Richards, Toshiyuki Mori and Katsuhiko Ariga, Antioxidant-substituted tetrapyrazinoporphyrazine as a fluorescent sensor for basic anions, Chem. Commun., 2012, 48, 3951–3953 (IF 6.834).

46) Caixia Ding, Fanhua Zeng, Jia Ni, Bingwu Wang*, Yongshu Xie*, Polynuclear complexes of ligands containing in situ formed oxazinane and oxazolidine rings with appended alkoxyl and phenol groups, Cryst. Growth Des., 2012, 12, 2089–2096 (IF 4.891).

47) Bo Liu, Weihong Zhu*, Yueqiang Wang, Wenjun Wu, Xin Li, Baoqin Chen, Yi-Tao Long and Yongshu Xie*, Modulation of energy levels by donors groups: an effective approach for optimizing the efficiency of zinc-porphyrin based solar cells, J. Mater. Chem., 2012, 22, 7434–7444 (IF 6.626).

48) Yue Wu, Shangjun Chen, Yuheng Yang, Qiong Zhang, Yongshu Xie, He Tian, Weihong Zhu*, A novel gated photochromic reactivity controlled by complexation/ dissociation with BF₃, Chem. Commun., 2012, 48, 528–530 (IF 6.834).

49) Yubin Ding, Yongshu Xie,* Xin Li, Jonathan P. Hill,* Weibing Zhang, Weihong Zhu, Selective and sensitive "turn-on'' fluorescent Zn sensors based on di- and tripyrrins with readily modulated emission wavelengths, Chem. Commun., 2011, 47, 5431–5433 (IF 6.834).

50) Wenqin Li, Yongzhen Wu, Xin Li, Yongshu Xie and Weihong Zhu*, Absorption and photovoltaic properties of organic solar cell sensitizers containing fluorene unit as conjunction bridge, Energy Environ. Sci.,2011, 4, 1830–1837 (IF 20.523).

51) Yongshu Xie*, M. Akada, J. P. Hill*, Q. M. Ji, R. Charvet, K. Ariga*, Real time self-assembly and reassembly of molecular nanowires of trigeminal amphiphile porphyrins, Chem. Commun., 2011, 47, 2285–2287 (IF 6.834).

52) Quanguo Wang, Yongshu Xie,* Yubin Ding, Xin Li, Weihong Zhu*, Colorimetric fluoride sensors based on deprotonation of pyrrole-hemiquinone compounds, Chem. Commun., 2010, 46, 3669–3671 (IF 6.834).

53) Fanhua Zeng, Jia Ni, Quanguo Wang, Yubin Ding, Seik Weng Ng, Weihong Zhu, Yongshu Xie*, Synthesis, structures, and photoluminescence of zinc(II), cadmium(II) and mercury(II) coordination polymers constructed from two novel tetrapyridyl ligands, Cryst. Growth Des., 2010, 10, 1611–1622 (IF 4.891).

54) Yongshu Xie*, Jia Ni, Fakun Zheng, Yong Cui, Quanguo Wang, Seik Weng Ng, Weihong Zhu, Tetra- and binuclear complexes of hydroxy-rich ligands: supramolecular structures, stabilization of unusual water clusters, and magnetic properties, Cryst. Growth Des., 2009, 9, 118–126 (IF 4.891).

55) Yongshu Xie, Jonathan P. Hill*, Amy Lea Schumacher, Atula S. D. Sandanayaka, Yasuyuki Araki, Paul A. Karr, Jan Labuta, Francis D’Souza*, Osamu Ito*, Christopher E. Anson, Annie K. Powell and Katsuhiko Ariga, Twisted, two-faced porphyrins as hosts for bispyridyl fullerenes: construction and photophysical properties, J. Phys. Chem. C, 2008, 112, 10559–10572 (IF 4.772).

56) Yongshu Xie, Jonathan P. Hill*, Amy Lea Schumacher, Paul A. Karr, Francis D’Souza*, Christopher E. Anson, Annie K. Powell, and Katsuhiko Ariga, Tautomerism in novel oxocorrologens, Chem. Eur. J., 2007, 13, 9824–9833 (IF 5.731).

57) Kaiju Wei, Yongshu Xie,* Jia Ni, Min Zhang, Qingliang Liu*, Syntheses, crystal structures, and photoluminescent properties of a series of M(II) coordination polymers containing M-X₂-M bridges: From 1-D chains to 2-D networks, Cryst. Growth & Des., 2006, 6, 1341–1350 (IF 4.891).