《稀土金屬雜環戊二烯：合成及反應》是張文雄為項目負責人，北京大學為依託單位的面上項目。
基本介紹
- 中文名：稀土金屬雜環戊二烯：合成及反應
- 項目類別：面上項目
- 項目負責人 ：張文雄
- 依託單位 ：北京大學
科研成果,項目摘要,
科研成果
序號 | 標題 | 類型 | 作者 |
|---|---|---|---|
1 | Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P-C Bonds | 期刊論文 | Du, Shanshan(#); Yang, Jimin; Hu, Jingyuan; Chai, Zhengqi; Luo, Gen; Luo, Yi(*); Zhang, Wen Xiong(*); Xi, Zhenfeng |
2 | Isolation and Characterization of a Trinuclear Rare-Earth Metal Complex Containing a Bicyclo[3.1.0]-P-6(4-) Ligand | 期刊論文 | Du Shanshan(#); Chai Zhengqi; Hu Jingyuan; Zhang Wen Xiong(*); Xi Zhenfeng |
3 | Indacyclopentadienes and Aromatic Indacyclopentadienyl Dianions: Synthesis and Characterization | 期刊論文 | Zhang, Yongliang(#); Yang, Zhenqiang; Zhang, Wen Xiong(*); Xi, Zhenfeng(*) |
4 | Isolation and Characterization of Four Phosphorus Cluster Anions P-7(3-), P-14(4-), P-16(2-) and P-26(4-) from the Nucleophilic Functionalization of White Phosphorus with 1,4-Dilithio-1,3-butadienes | 期刊論文 | Du Shanshan(#); Hu Jingyuan; Chai Zhengqi; Zhang Wen-Xiong(*); Xi Zhenfeng |
5 | Synthesis and Structural Characterization of Butadienylcalcium-based Heavy Grignard Reagents and a Ca-4[O] Inverse Crown Ether Complex | 期刊論文 | Wei Baosheng(#); Liu Liang; Zhang Wen Xiong(*); Xi Zhenfeng |
6 | Direct Synthesis of Phospholyl Lithium from White Phosphorus | 期刊論文 | Xu, Ling(#); Chi, Yue; Du, Shanshan; Zhang, Wen-Xiong(*); Xi, Zhenfeng |
7 | Metallacyclopentadienes:Synthesis, Structure and Reactivity | 期刊論文 | Ma, Wangyang(#); Yu, Chao(#); Chen, Tianyang(#); Xu, Ling; Zhang, Wen-Xiong(*); Xi, Zhenfeng |
8 | Formation and ligand-based reductive chemistry of bridged bis-alkylidene scandium(III) complexes | 期刊論文 | Ma Wangyang(#); Yu Chao; Chi Yue; Chen Tianyang; Wang Lianjun; Yin Jianhao; Wei Baosheng; Xu Ling; Zhang Wen-Xiong(*); Xi Zhenfeng |
9 | Diversified Aggregation States of Phospholyl Lithiums | 期刊論文 | Du Shanshan(#); Zhang Wen-Xiong(*); Xi Zhenfeng |
10 | Dilithio Spiro Zincacyclopentadienes and Dizinca[10]cycles: Synthesis and Structural Characterization | 期刊論文 | Zhang, Yongliang(#); Liu, Liang; Chen, Tianyang; Huang, Zhe; Zhang, Wen Xiong(*); Xi, Zhenfeng(*) |
11 | 過渡金屬催化的成胍反應高效構建胍類衍生物 | 期刊論文 | 王連軍(#); 遲樾; 張文雄(*); 席振峰 |
12 | 過渡金屬催化的醯胺C-N鍵活化 | 期刊論文 | 陳天陽(#); 張文雄(*) |
13 | Alkenyl Magnesium Compounds: Generation and Synthetic Application | 期刊論文 | Zhu Miaomiao(#); Liu Liang; Yu Hai-Tao; Zhang Wen-Xiong(*); Xi Zhenfeng(*) |
14 | Sandwich Lutetacyclopentadiene with the Coordination of Lithium to the Diene Unit: Synthesis, Structure, and Transformation | 期刊論文 | Xu, Ling(#); Wang, Yang; Wang, Yu-Chen; Wang, Zitao; Zhang, Wen-Xiong(*); Xi, Zhenfeng |
15 | CuOTf-Catalyzed Selective Generation of 2-Aminopyrimidines from Carbodiimides and Diaryliodonium Salts by a Triple C(sp(3))-H Functionalization | 期刊論文 | Chi Yue(#); Yan Haihan; Zhang Wen Xiong(*); Xi Zhenfeng(*) |
16 | Synthesis of Quinoline Derivatives via Cu-Catalyzed Cascade Annulation of Heterocumulenes, Alkynes, and Diaryliodonium Salts | 期刊論文 | Chi Yen(#); Yan Haihan(#); Zhang Wen Xiong(*); Xi Zhenfeng |
17 | Selective Transformation of Well-Defined Alkenyllithiums to Alkenylmagnesiums via Transmetalation | 期刊論文 | Zhu Miaomiao(#); Liu Liang; Zhang Yongliang; Yu Hai-Tao; Zhang Wen-Xiong(*); Xi Zhenfeng(*) |
18 | Reversible Two-Electron Redox Reactions Involving Tetralithio/Dilithio Palladole, Platinacycle, and Dicupra[10]annulene | 期刊論文 | Huang, Zhe(#); Zhang, Yongliang; Zhang, Wen Xiong(*); Xi, Zhenfeng(*) |
19 | Dual Functionalization of White Phosphorus: Formation, Characterization, and Reactivity of Rare-Earth-Metal Cyclo-P-3 Complexes | 期刊論文 | Du Shanshan(#); Yin Jianhao; Chi Yue; Xu Ling; Zhang Wen-Xiong(*) |
項目摘要
金屬有機雜環化合物，如金屬雜環戊二烯，是許多金屬計量或催化有機合成反應中的關鍵中間體,在金屬有機化學和配位化學領域中占有重要的地位。儘管許多種類的金屬雜環戊二烯已報導，而稀土金屬雜環戊二烯還沒有報導。本項目選擇具有高挑戰性的稀土金屬雜環戊二烯為研究目標，將會有力地促進稀土金屬有機化學的發展。主要研究內容包括：（1）通過環戊二烯配體上取代基和1,3-丁二烯-1,4-雙金屬化合物上取代基的調控，建立通用的方法合成從最小離子半徑Sc到最大離子半徑La的三類稀土金屬雜環戊二烯，利用譜學手段和單晶結構解析鑑定其結構；（2）研究其與碳二亞胺及其它不飽和小分子，如醛，酮，CO和CO2的反應，建立在化學計量的反應之上，尋求發展催化的方法，歸納總結稀土金屬離子半徑和反應性的規律。
