王銅道，男，畢業於廈門大學，博士，大連理工大學碩士生導師，張大煜學院特聘研究員。
2008和2013年分別獲得廈門大學化學學士和有機化學博士學位（導師：夏海平教授），並均獲評為當屆的優秀畢業生。在廈門大學求學期間獲得多項獎學金和榮譽稱號，其中包括盧嘉錫獎學金（廈門大學化學化工學院三大獎之一）﹑博士研究生國家獎學金及入選廈門大學優秀博士培養計畫等。博士畢業後，作為iChEM Fllow進入能源材料化學協同創新中心工作一年，隨後於2014年至2017年在國際著名化學家Prof. Gerhard Erker課題組做博士後。以第一作者發表學術論文13篇，其中包括4篇Angew. Chem. Int. Ed.，2篇J. Am. Chem. Soc. 以及Chem. Sci. ﹑Sci. Rep.各一篇。2018年1月以特聘研究員A崗引進到張大煜學院工作。主要從事金屬有機化學和元素有機化學方面的研究，研究內容包括：（1）金屬硼多重鍵的結構調控及反應性研究。（2）金屬硼受阻路易斯酸鹼對化學。
基本介紹
- 中文名：王銅道
- 畢業院校：廈門大學
- 學位/學歷：博士
- 專業方向：有機化學
- 任職院校：大連理工大學張大煜學院
人物經歷,教育經歷,工作經歷,研究方向,學術成果,發表論文,科研項目,
人物經歷
教育經歷
2008.9---2013.9 廈門大學有機化學博士
2004.9---2008.7 廈門大學化學學士
2001.9---2014.6 安徽省明光中學理科
工作經歷
2017.12 大連理工大學張大煜學院特聘研究員A崗
2014.11---2017.12 德國明斯特大學博士後
2013.9---2014.8 廈門大學能源材料化學協同創新中心博士後
研究方向
1.金屬硼多重鍵的結構調控及反應性研究
通過對金屬中心配體和硼部分取代基的調控，設計合成結構新穎且穩定的金屬硼雙重鍵以及三重鍵化合物，並研究其反應性。通過對重要中間體的分離，深入研究反應機理，開拓新反應。
2. 金屬硼受阻路易斯酸鹼對化學
以構築結構為基礎，研究其與不飽和有機物﹑氫氣﹑一氧化碳﹑二氧化碳，氧氣和氮氣等的反應性，並探索其作為催化劑在有機合成中的套用（比如催化氫化反應﹑硼基化反應﹑矽烷化反應及氫胺化反應等）。在金屬有機化學和硼化學上發展新概念、新反應並深入研究這些新概念、新反應與材料科學、生物科學、能源科學等交叉融合。
招收有機化學、套用化學、精細化工、製藥工程等專業的博士生和碩士生，同時招收相關專業博士後，歡迎有志青年加盟！！
學術成果
發表論文
1. Tongdao Wang, Constantin G. Daniliuc, Christian Mueck-Lichtenfeld, Gerald Kehr, Gerhard Erker* Formation of Reactive p-Conjugated Frustrated N/B Pairs by Borane-Induced Propargyl Amine Rearrangement, J. Am. Chem. Soc. 2018, 140, 3635−3643.
2. Tongdao Wang, Gerald Kehr, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerhard Erker* Selective Oxidation of an Active Intramolecular Amine/Borane Frustrated Lewis Pair with Dioxygen, J. Am. Chem. Soc. 2016, 138, 4302−4305.
3. Tongdao Wang, Jun Zhu, Feifei Han, Chen Zhou, Hanyu Chen, Hong Zhang*, Haiping Xia* Synthesis of Five-membered Osmacycloallenes and Conversion into Six-membered Osmacycloallenes, Angew. Chem. Int. Ed. 2013, 52, 13361-13364.
4. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* Key Intermediates of Iodine-Mediated Electrophilic Cyclization: Isolation and Characterization in an Osmabenzene System, Angew. Chem. Int. Ed. 2013, 52, 9251–9255. (+contributed equally)
5. Tongdao Wang+, Hong Zhang+, Feifei Han, Ran Lin, Zhenyang Lin*, Haiping Xia* Synthesis and Characterization of a Metallapyridyne Complex, Angew. Chem. Int. Ed. 2012, 51(39): 9838-9841. (+contributed equally)
6. Tongdao Wang, Shunhua Li, Hong Zhang, Ran Lin, Feifei Han, Yumei Lin, Ting Bin Wen, Haiping Xia* Annulation of Metallabenzenes: From Osmabenzene to Osmabenzothiazole to Osmabenzoxazole, Angew. Chem. Int. Ed. 2009, 48, 6453-6456.
7. Tongdao Wang, Long Wang, Constantin G. Daniliuc, Kamil Samigullin, Matthias Wagner, Gerald Kehr, Gerhard Erker* CO/CO and NO/NO coupling at a hidden frustrated Lewis pair template, Chem. Sci. 2017, 8, 2457-2463.
8. Tongdao Wang, Feifei Han, Haiping Huang, Jinhua Li, Hong Zhang*, Jun Zhu, Zhenyang Lin*, Haiping Xia* Synthesis of Aromatic Aza-metallapentalenes from Metallabenzene via Sequential Ring Contraction/Annulation, Sci. Rep. 2015, 5, 9584.
9. Tongdao Wang, Gerald Kehr, Constantin G. Daniliuc, Gerhard Erker* Metal-Free Carbonylation Route to a Reactive Borataepoxide System, Organometallics 2018, 37, 1040-1049.
10. Tongdao Wang+, Sonja Kohrt+, Constantin G. Daniliuc, Gerald Kehr and Gerhard Erker* Borata-Wittig olefination reactions of ketones, carboxylic esters and amides with bis(pentafluorophenyl)borata-alkene reagents Org. Biomol. Chem. 2017, 15, 6223-6232.(+contributed equally)
11. Tongdao Wang, Xenia Jentgens, Constantin G. Daniliuc, Gerald Kehr, and Gerhard Erker* Tris(pentafluorophenyl)borane-Catalyzed Reaction of Phosphorus/Boron and Nitrogen/Boron Frustrated Lewis Pair Dihydrogen Activation Products with Alkenes and Alkynes, ChemCatChem 2017, 9, 651-658.
12. Tongdao Wang, Lei Liu, Stefan Grimme, Constantin G. Daniliuc, Gerald Kehr, Gerhard Erker* Cyclic Amine/Borane Lewis Pairs by the Reaction of N,NDiallylaniline with Lancaster’s H2B-C6F5 Reagent, Chem. Asian J. 2016, 11, 1394–1399.
13. Tongdao Wang+, Hong Zhang+, Feifei Han, Lipeng Long, Zhenyang Lin*, Haiping Xia* cine-Substitution Reactions of Metallabenzenes: An Experimental and Computational Study, Chem. Eur. J. 2013, 19, 10982–10991. (+contributed equally)
14. Shunxi Dong, Long Wang, Tongdao Wang, Constantin G. Daniliuc, Melanie Brinkkötter, Hellmut Eckert, Gerald Kehr, Gerhard Erker* Formation and reactions of active five-membered phosphane/borane frustrated Lewis pair ring systems, Dalton Trans., 2018, DOI: 10.1039/c8dt00672e
15. Lipeng Long, Xiaoxi Zhou, Tongdao Wang, Zhixin Chen, Hong Zhang,* Haiping Xia* Synthesis of Imidazopyridinium-Fused Metallacycloallene via One-Pot Reaction of η2-Alkynol-Coordinated Osmacycle with 2-Aminopyridine, Organometallics 2017, 36, 4184−4190.
16. Feifei Han, Jinhua Li, Hong Zhang,* Tongdao Wang, Zhenyang Lin,* Haiping Xia* Reactions of Osmabenzene with Silver/Copper Acetylides: From Metallabenzene to Benzene, Chem. Eur. J. 2015, 21, 565–567.
17. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang*, Haiping Xia* A Novel m-Metallaphenol: Synthesis and Reactivity Studies, Chem. Eur. J. 2014, 20, 4363–4372.
18. Feifei Han, Tongdao Wang, Jinhua Li, Hong Zhang, Laiying Zhang, Xumin He*, Haiping Xia* Synthesis, Structure, and Reactivity of an Osmacyclopentene Complex, Organometallics 2014, 33, 5301−5307.
19. Hong Zhang*, Ran Lin, Guangning Hong, Tongdao Wang, Ting Bin Wen, Haiping Xia* Nucleophilic Aromatic Addition Reactions of the Metallabenzenes and Metallapyridinium: Attacking Aromatic Metallacycles with Bis(diphenylphosphino)methane to Form Metallacyclohexadienes and Cyclic η2-Allene-Coordinated Complexes, Chem. Eur. J. 2010, 16, 6999-7007.
科研項目
鋨硼烯的結構設計和反應性探索, 國家自然科學基金項目, 2018/08/16, 進行
