氧雜富勒烯的合成與性能研究

《氧雜富勒烯的合成與性能研究》是甘良兵為項目負責人，北京大學為依託單位的面上項目。

基本介紹

• 中文名：氧雜富勒烯的合成與性能研究
• 項目類別 ：面上項目
• 項目負責人：甘良兵
• 依託單位 ：北京大學

科研成果

序號	標題	類型	作者
1	A green fullerene derivative as a fluoride ion sensor	期刊論文	Liang Xu|Sisi Liang|Liangbing Gan|
2	Synthesis of Isomerically Pure Multi-aniline C-60 Adducts with Cyclopentadienyl Addition Pattern	期刊論文	Liang, Sisi|Xu, Liang|Gan, Liangbing|
3	Selective Addition of Secondary Amines to C-60: Formation of Penta- and Hexaamino[60]fullerenes	期刊論文	Li, Yanbang|Gan, Liangbing|
4	Molecular containers with a dynamic orifice: open-cage fullerenes capable of encapsulating either H2O or H-2 under mild conditions	期刊論文	Yu, Yuming|Shi, Lijun|Yang, Dazhi|Gan, Liangbing|
5	Synthesis of Open-cage Fullerenes with 4-Alkynylphenyl Groups on the Rim of the Orifice	期刊論文	Yu, Yuming|Zhang, Tong|Gan, Liangbing|
6	Synthesis andChemical Reactivity of Tetrahydro[60]fullerene Epoxides with Both Amino andAryl Addends	期刊論文	Sisi Liang|Liang Xu|Liangbing Gan|
7	Synthesis of C-60(O)(3): An Open-Cage Fullerene with a Ketolactone Moiety on the Orifice	期刊論文	Zhou, Zishuo|Zhang, Jianxin|Zhang, Showxin|Gan, Liangbing|
8	N-Fluorobenzenesulfonimide Based Functionalization of C-60	期刊論文	Li, Yanbang|Lou, Ning|Gan, Liangbing|
9	Regioselective Diels-Alder Reactions Directed by Carbonyl Groups on the Rim of Open-Cage Fullerene Derivatives	期刊論文	Zhang, Gang|Liang, Sisi|Yu, Yuming|Gan, Liangbing|
10	Selective Multiamination of C-70 Leading to Curved p Systems with 60, 58, 56, and 50 p Electrons	期刊論文	Li, Yanbang|Xu, Dan|Gan, Liangbing|
11	Release of the Water Molecule Encapsulated Inside an Open-Cage Fullerene through Hydrogen Bonding Mediated by Hydrogen Fluoride	期刊論文	Liang, Sisi|Sun, Jiahao|Liu, Yajun|Gan, Liangbing|
12	Open-cage fullerene with a stopper acts as a molecular vial for a single water molecule	期刊論文	Xu, Liang|Liang, Sisi|Sun, Jiahao|Gan, Liangbing|
13	Aniline Induced Domino Ring Contraction Process on the Rim of an Open-Cage Fullerene with Carbonyl, Imino and Iactone Moieties	期刊論文	Liu, Shuming|Gan, Liangbing|
14	Preparation of Azafullerene C59NR5 and Fullerene Derivative C60NAr5 with a Pyridine Moiety on the Cage Skeleton	期刊論文	Li, Yanbang|Cui, Chengxing|Liu, Yajun|Gan, Liangbing|
15	Punching a Carbon Atom of C-60 into its Own Cavity to Form an Endohedral Complex CO@C59O6 under Mild Conditions	期刊論文	Colombo, Francesca|Yu, Yuming|Zhang, Wen-Xiong|Gan, Liangbing|
16	Peroxide mediatedselective cleavage of [60]fullerene skeleton bonds: towards the synthesis ofopen-cage fulleroid C55O5	期刊論文	Liangbing Gan|
17	Synthesis of C-58 Open-Cage Fullerene Derivatives	期刊論文	Xu, Liang|Huang, Xinchen|Liang, Sisi|Gan, Liangbing|
18	Synthesis of an Azahomoazafullerene C59N(NH)R and Gas-Phase Formation of the Diazafullerene C58N2	期刊論文	Xin, Nana|Liang, Sisi|Wang, Nengdong|Gan, Liangbing|
19	Fullerene-Based Macro-Heterocycle Prepared through Selective Incorporation of Three N and Two O Atoms into C60	期刊論文	Beidi Xu|Ning Lou|Dan Xu|Liangbing Gan|
20	Pentafluorophenyl Transfer Reaction: Preparation of Pentafluorophenyl [60]Fullerene Adducts through Opening of Fullerene Epoxide Moiety with Trispentafluorophenylborane	期刊論文	Liang, Sisi|Xu, Liang|Jia, Zhenshan|Gan, Liangbing|
21	Open-cage fullerenes as tailor-made container for a single water molecule	期刊論文	Shi, Lijun|Gan, Liangbing|
22	Near-Infrared Absorbing Compounds Based on pi-Extended Tetrathiafulvalene Open-Cage Fullerenes	期刊論文	Yu, Yuming|Xu, Liang|Huang, Xincheng|Gan, Liangbing|

項目摘要

富勒烯是一類全部由碳原子組成的球狀化合物，雜富勒烯是將富勒烯中的部分碳原子用其它雜原子取代所得到的化合物。有關雜富勒烯的研究文獻上理論計算結果較多，但這類化合物的化學合成目前文獻上僅限於單氮雜富勒烯。由於雜原子的引入能改變體系共軛的狀況以及各種功能特性，雜富勒烯的製備在富勒烯的開發套用研究中具有重要意義。本項目擬合成氧雜富勒烯及其衍生物，主要設計路線是以前期工作中所合成的富勒烯過氧化物為基本原料，通過過氧鍵在不同條件下的化學反應，開發富勒烯骨架上碳碳鍵的選擇性切斷途徑，以及用氧原子取代富勒烯碳原子的方法。另外還將研究氧雜富勒烯的化學反應製備其衍生物，研究氧雜富勒烯及其衍生物的功能特性如氧化還原和光電轉換性能，探索有關雜富勒烯的構效關係規律，為富勒烯的開發套用提供基礎。