簡介
教育背景
2000.09-2005.06,中國科學院蘭州化學物理研究所,理學博士,博士論文方向:均相催化、羰基化反應、CO2高效利用
工作經歷
2009.12-至今, 中國科學院蘭州化學物理研究所羰基合成與選擇氧化國家重點實驗室,“百人計畫”研究員
2006.04-2009.12,
新加坡國立大學化學系,博士後(Research Fellow A)
2005.06-2006.03,中國科學院過程工程研究所,助理研究員
研究方向
金屬有機化學、均相催化;
綠色化學、清潔催化;
新型碳基催化材料的製備及套用。
科研項目
國家自然基金青年基金(2011-2013)
中科院“百人計畫”擇優支持(2011-2014)
科技部國家重點實驗室方向性項目(2010-2014)
中科院儀器研製項目(2011-2012)
獲獎情況
中科院“百人計畫”擇優支持(2010)
甘肅省自然科學二等獎(2007)
中科院院長優秀獎(2005)
中科院劉永齡獎學金(2003)
近期論著
代表性研究論文:
1. Li, J. L., Liu, G. L., Shi, L. J., Xing, Q., Li, F. W.*, Cobalt Modified N-doped Carbon Nanotubes for Catalytic C=C Bond Formation via Dehydrogenative Coupling of Benzyl Alcohols and DMSO, Green Chem. , 2017, 2017, DOI: 10.1039/C7GC02335A.
2. Wu, J., Gao, G., Sun, P., Long, X. D., Li, F. W.*, Synergetic catalysis of bimetallic CuCo nanocomposites for selective hydrogenation of bio-derived esters, ACS Catal., 2017, 7, 7890-7901.
3. Gao, G., Sun, P., Li, Y. Q., Wang, F., Zhao, Z. L., Qin, Y.*, Li, F. W.*, Highly stable porous-carbon-coated Ni catalysts for the reductive amination of levulinic acid via an unconventional pathway, ACS Catal., 2017, 7, 4927-4935.
4. Li, J. L., Liu, G. L., Long, X. D., Gao, G., Wu, J., Li, F. W.*, Different active sites in a bifunctional Co@N-doped graphene shells based catalyst for the oxidative dehydrogenation and hydrogenation reactions, J. Catal., 2017, 355, 53-62.
5. Wu J., Gao, G., Li J. L., Sun P., Long X. D., Li, F. W.*, Efficient and versatile CuNi alloy nanocatalysts for the highly selective hydrogenation of furfural, Appl. Catal. B: Environ., 2017, 203, 227–236.
6. Xing, Q., Lv, H., Xia, C. G., Li, F. W.*, Palladium-Catalyzed Intermolecular Carbonylative Cross-Coupling of Heteroaryl C(sp2)–H Bonds with Amines: An Efficient Strategy for Oxidative Aminocarbonylation of Azoles, Chem. Commun., 2017, 53, 6914-6917.
7. Wang, W. L., Zhao, L. Y., Lu, H., Zhang, G. D., Xia, C. G., Hahn, F. E.*, and Li, F. W.*, Modular “Click” Preparation of Heterometallic, Bifunctional Polymeric Catalysts, Angew. Chem. Int. Ed., 2016, 55, 7665-7670 (highlighted by ChemistryViews).
8. Sun, P., Gao, G., Zhao, Z. L., Xia, C. G., and Li, F. W.*, Acidity-regulation for enhancing the stability of Ni/HZSM-5 catalyst for valeric biofuel production, Appl. Catal. B: Environ., 2016, 189, 19-25.
9. Lv, H., Xing, Q., Yue, C. T., Lei, Z. Q.*, and Li, F. W.*, Solvent-promoted Catalyst-free N-Formylation of Amines Using Carbon Dioxide under Ambient Conditions, Chem. Commun., 2016, 52, 6545-6548.
10. Zhao, J. J., Li, P., Li, X. J., Xia, C. G., and Li, F. W.*, Straightforward synthesis of functionalized chroman-4-ones through cascade radical cyclization-coupling of 2-(allyloxy)arylaldehydes, Chem. Commun., 2016, 52, 3661-3664.
11. Xing, Q., Lv, H., Xia, C. G., and Li, F. W.*, Iron-Catalyzed Aerobic Oxidative Cleavage of C–C σ-Bond Using Air as Oxidant: Chemoselectively to Carbon Chain-Shortened Aldehydes, Ketones and 1,2-Dicarbonyl Compounds, Chem. Commun., 2016, 52, 489-492.
12. Li, Z. L., Li, G. L., Jiang, L. H., Li, J. L., Sun, G. Q.*, Xia, C. G.*, and Li, F. W.*, Ionic Liquids as Precursors for Efficient Mesoporous Iron-Nitrogen-Doped Oxygen Reduction Electrocatalyst, Angew. Chem. Int. Ed., 2015, 54, 1494-1498.
13. Shi, L. J., Zhong, X., Shi, H. D., Lei, Z. Q.*, and Li, F. W.*, Manganese catalyzed C-H functionalization of indoles with alkynes to synthesize bis/trisubstituted indolylalkenes and carbazoles: the acid is the key to control selectivity, Chem. Commun., 2015, 51, 7136-7319.
14. Zhao, J. J., Li, P., Xia, C. G., and Li, F. W.*, Facile Synthesis of Trisubstituted Carbazoles via Acid-Catalyzed Ring Opening-Annulation of 2-Amidodihydrofurans with Indoles, Chem. Eur. J., 2015, 21, 16383-16386 (Highlighted by SYNFACTS, 2015, 11, 1248).
15. Xing, Q., Lv, H., Xia, C. G., and Li, F. W.*, Intramolecular Cooperation-Driven C-C Cleavage of 1,3-Dicarbonyl Compounds with 2-Iodoanilines to o-(N-Acylamino)aryl Ketones and Multisubstituted Indoles, Chem. Eur. J., 2015, 21, 8591-8596 (Hot Paper).
16. Zhang, G. D., Lang, R., Wang, W. L., Xia, C. G., and Li, F. W.*, Light-sensitive and recoverable N-heterocyclic carbene copper(I) complex in homogeneous catalysis, Adv. Synth. Catal., 2015, 357, 917-922 (Very Important Paper).
17. Sun P., Gao, G., Zhao, Z. L., Xia, C. G., and Li, F. W.*, Stabilization of Cobalt Catalysts by Embedment for Efficient Production of Valeric Biofuel, ACS Catal.,2014, 4, 4136-4142.
18. Yang, Y., Gao, G., Zhang, X., and Li, F. W.*, Facile Fabrication of Composition-Tuned Ru-Ni Bimetallics in Ordered Mesoporous Carbon for Levulinic Acid Hydrogenation, ACS Catal., 2014, 4, 1419-1425.
19. Wang, W. L., Zheng, A. M., Zhao, P. Q., Xia, C. G., and Li, F. W.*, Au-NHC@Porous Organic Polymers: Synthetic Control and Its Catalytic Application in Alkyne Hydration Reactions, ACS Catal., 2014, 4, 321-327.
20. Li, P., Zhao, J. J., Xia, C. G., and Li, F. W.*,A Direct Oxidative Coupling of Enamides and 1,3-Dicarbonyl Compounds: A Facile and Versatile Approach to Dihydrofurans, Furans, Pyrroles, and Dicarbonyl Enamides, Org. Lett., 2014, 16, 5992-5995.
21. Zhao, J. J., Li P., Xia, C. G., and Li, F. W.*, Direct N-acylation of azoles via metal-free catalyzed oxidative cross-coupling strategy, Chem. Commun., 2014, 50, 4751-4754.
22. Xing, Q., Li, P., Lv, H., Lang, R., Xia, C. G., and Li, F. W.*, Acid-catalyzed acylation reaction via C–C bond cleavage: a facile and mechanistically defined approach to synthesize 3-acylindoles, Chem. Commun., 2014, 50, 12181-12184.
23. Liu, J. M.*, Zhang, X., Shi, L. J., Liu, M. W., Yue, Y. Y., and Li, F. W.*, Zhuo, K. L.,* Base-promoted synthesis of coumarins from salicylaldehydes and aryl-substituted 1,1-dibromo-1-alkenes under transition-metal-free conditions, Chem. Commun., 2014, 50, 9887-9890.
24. Sun, P., Long, X. D., He, H., Xia, C. G., and Li, F. W.*, Conversion of Cellulose into Isosorbide over Bifunctional Ruthenium Nanoparticles Supported on Niobium Phosphate, ChemSusChem, 2013, 6, 2190-2197 (back cover).
25. Li, Z. L., Liu, J. H., Xia, C. G.*, and Li, F. W.*, Nitrogen-Functionalized Ordered Mesoporous Carbons as Multifunctional Supports of Ultrasmall Pd Nanoparticles for Hydrogenation of Phenol, ACS Catal., 2013, 3, 2440-2448.
26. Li, Z. L., Liu, J. H., Huang, Z. W., Yang, Y., Xia, C. G.*, and Li, F. W.*, One-pot synthesis of Pd nanoparticle catalysts supported on N-doped carbon and the application in the domino carbonylation, ACS Catal., 2013, 3, 839-845.
27. Wang, W. L., Zhang, G. D., Lang, R., Xia, C. G., and Li, F. W.*, pH-Responsive N-heterocyclic carbene copper(I) complexes: syntheses and recoverable applications in the carboxylation of arylboronic esters and benzoxazole with carbon dioxide, Green Chem., 2013, 13, 635-640.
28. Hou, C. D., Ren, Y. L., Lang, R., Hu, X. X., Xia, C. G., and Li, F. W.*, Palladium-catalyzed direct phosphonation of azoles with dialkyl phosphites, Chem. Commun., 2012, 48, 5181-5183.
29. Xing, Q., Shi, L. J., Lang, R., Xia, C. G., and Li, F. W.*, Palladium-catalyzed mono- and double-carbonylation of indole with amine controllably leading to amide and α-ketoamide, Chem. Commun., 2012, 48, 11023-11025.
30. Lang, R., Shi, L. J., Li, D., Xia, C. G.*, and Li, F. W.*, A General Method for Palladium-Catalyzed Direct Carbonylation of Indole with Alcohol and Phenol, Org. Lett , 2012, 14, 4130-4133.
31. Lang R., Wu J. L., Shi L. J., Xia C. G.*, and Li, F. W.*, Regioselectively Rh-catalyzed direct carbonylation of indole to synthesize indole-3-carboxylate, Chem. Commun., 2011, 47, 12553-12555.
32. Wang, W. L., Wu, J. L., Xia, C. G., and Li, F. W.*, Reusable ammonium salt tagged NHC-Cu(I) complexes: preparation and catalytic application in the three component click reaction, Green. Chem.,2011, 13, 3440-3445.