《基於可控/“活性”自由基聚合的高分子合成》是李子臣為項目負責人，北京大學為依託單位的重點項目。
基本介紹
- 中文名：基於可控/“活性”自由基聚合的高分子合成
- 項目類別 ：重點項目
- 依託單位 ：北京大學
- 項目負責人：李子臣
科研成果 ,項目摘要,
科研成果
序號 | 標題 | 類型 |
|---|---|---|
1 | Shaped Polymer Nano-objects from Gelable Block Copolymers | 會議論文 |
2 | Separation of Cyclic Glycopolymer fom the AB* Inimer Initiated ATRP of a Methacrylate Sugar Monomer and Preparation of Tadpole Type Block Copolymer | 會議論文 |
3 | Macromolecular Engineering of Poly (vinyl alcohol) | 會議論文 |
4 | Poly (vinyl alcohol) Containing Block Copolymers: Synthesis and Properties | 會議論文 |
5 | Synthesis of Gelable Block Copolymers and Study of Their Properties | 會議論文 |
6 | Synthesis of Well-defined Poly(vinyl acetate)-b-polystyrene by Combination of ATRP and RAFT Polymerization | 會議論文 |
7 | Codendronized Polymers: Engineering of One Dimensional Molecular Nanoobjects | 會議論文 |
8 | Tadpole-Shaped Copolymers via ATRP, Click Chemistry and Ring Opening Polymerization | 會議論文 |
9 | New Architectural Polymers By Controlled Radical Polymerization | 會議論文 |
10 | Dendronized Polymer Brushes－Single Molecular Nano-Objects | 會議論文 |
11 | Hierarchical Structure in Oriented Fibers of a Dendronized Polymer. | 期刊論文 |
12 | New Architectural Polymers by?Controlled Radical Polymerization | 會議論文 |
13 | Controlling the degree of branching in the SCVP of p-(2-bromoisobutyloylmethyl) styrene (VBBiB) by Slow AGET ATRP | 會議論文 |
14 | Synthesis of Tadpole-shaped Copolymers via ATRP and Click Chemistry | 會議論文 |
15 | 原子轉移自由基聚合控制聚合物的拓撲結構及支化度 | 會議論文 |
16 | New Polymer Synthesis by Controlling the Kinetic Process of ATRP | 會議論文 |
17 | Macromolecular Engineering of Poly (vinyl alcohol) | 會議論文 |
18 | Preparation of Tadpole-Shaped Amphiphilic Cyclic PS-b-linear PEO via ATRP and Click Chemistry. | 期刊論文 |
19 | 反應性嵌段共聚物及其聚集體 | 會議論文 |
20 | ATRP of 3-(triethoxysilyl)propyl methacrylate and preparation of stable gelable block copolymers. | 期刊論文 |
21 | Intelligent nucleic acid delivery systems based on stimuli-responsive polymers | 期刊論文 |
22 | Multiblock Copolymers of Maleic Anhydride and Styrene by Reversible Addition Fragmentation Chain Transfer (RAFT) Polymerization | 會議論文 |
23 | 基於醋酸乙烯酯可控自由基聚合的高分子設計與合成 | 會議論文 |
24 | Functional Block Copolymer Assemblies | 會議論文 |
25 | Synthesis of bis(2,2 ': 6 ',2 ''-terpyridine) -terminated telechelic polymers by RAFT polymerization and ruthenium-polymer complexation thereof | 期刊論文 |
26 | Reactive block copolymers and their vesicles | 會議論文 |
27 | Cylindrical Molecular Brushes with a Loose Grafting Density. | 期刊論文 |
28 | An all ATRP route to PMMA-PEO-PS and PMAA-PEO-PS miktoarm ABC star terpolymer. | 期刊論文 |
29 | Dispersing multi-walled carbon nanotubes with water–soluble block copolymers and their use as supports for metal nanoparticles | 期刊論文 |
30 | Codendronized Polymers: Wormlike Molecular Objects with a Segmented Structure | 期刊論文 |
31 | Nanoobjects with Controlled Shapes by Self-Assembly of Gelable Block Copolymers | 期刊論文 |
32 | Organic-inorganic hybrid materials by self-gelation of block copolymer assembly and nanoobjects with controlled shapes thereof | 期刊論文 |
33 | Onionlike Spherical Polymer Composites with Controlled Dispersion of Gold Nanoclusters | 期刊論文 |
34 | Supramolecular ABA triblock copolymer with polyrotaxane as B block and its hierarchical self-assembly. | 期刊論文 |
35 | In situ and online monitoring polymerization-induced micellization. | 期刊論文 |
36 | Codendronized polymers pendent with alternating dendritic wedges brushes containing metallo-supramolecular polymer side chains | 期刊論文 |
37 | Robust organic/inorganic hybrid porous thin films via breath-figure method and gelation process | 期刊論文 |
38 | Synthesis of novel rod-coil Amphiphilic block copolymers PAA-b-DPS with Frechet-type dendronized polystyrene and poly(acrylic acid). | 期刊論文 |
39 | Synthesis, characterization, and self-assembly of comb-dendronized amphiphilic block copolymers. | 期刊論文 |
40 | Formation of CdS nanoparticle necklaces with functionalized dendronized polymers | 期刊論文 |
41 | Preparation of platinum nanoparticles using star-block copolymer with a carboxylic core | 期刊論文 |
42 | Divergent synthesis of dendrimer-like macromolecules through a combination of atom transfer radical polymerization and click reaction | 期刊論文 |
43 | Acid-Sensitive Polymeric Micelles Based on Thermoresponsive Block Copolymers with Pendent Cyclic Orthoester Groups. | 期刊論文 |
44 | Reactive block copolymer vesicles with an epoxy wall | 期刊論文 |
45 | Double-hydrophilic polymer brushes: Synthesis and application for crystallization modification of calcium carbonate | 期刊論文 |
46 | Gelation inside block copolymer aggregates and organic/inorganic nanohybrids | 期刊論文 |
47 | Hydrophilic block copolymer aggregation in solution induced by selective threading of cyclodextrins | 期刊論文 |
48 | Dual-Responsive Supramolecular Hydrogels from Water-Soluble PEG-Grafted Copolymers and Cyclodextrin. | 期刊論文 |
49 | Functionalization of crosslinked vesicles by co-self-assembly of a gelable diblock copolymer and mercaptosilane. | 期刊論文 |
50 | Synthesis of dendronized polymer brushes containing metallo-supramolecular polymer side chains | 期刊論文 |
項目摘要
通過對可逆加成斷裂鏈轉移（RAFT）聚合鏈轉移劑的設計合成以及原子轉移自由基聚合（ATRP）引發體系和聚合條件的最佳化實現醋酸乙烯酯、alpha-烯烴等的可控/活性自由基聚合和共聚合；發展通過可控/活性自由基聚合製備高立構規整性（甲基）丙烯酸酯類聚合物的方法；設計並主要採用RAFT 聚合和ATRP 合成系列新型確定結構、組成、功能的聚合物，如嵌段共聚物和支化聚合物（星形聚合物；聚合物分子刷等）；發展利用可控/活性自由基聚合製備新型結構聚合物的新方法，通過對聚合物性質的研究，深入理解聚合物結構的特異性和性能的關係，發現新的功能高分子材料
