以鈀卡賓為基礎的催化反應研究

科研成果

序號	標題	類型	作者
1	Gold(III)-Catalyzed Direct Acetoxylation of Arenes with Iodobenzene Diacetate	期刊論文	Qiu, Di\|Zheng, Zhitong\|Mo, Fanyang\|Xiao, Qing\|Tian, Yu\|Zhang, Yan\|Wang, Jianbo\|
2	Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group	期刊論文	8. Xi Wang, Yan Xu, Fanyang Mo, Guojing Ji, Di Qi\|Jianbo Wang*\|
3	CuBr-Catalyzed Coupling of N-Tosylhydrazones and Terminal Alkynes: Synthesis of Benzofurans and Indoles	期刊論文	Zhou, Lei\|Shi, Yi\|Xiao, Qing\|Liu, Yizhou\|Ye, Fei\|Zhang, Yan\|Wang, Jianbo\|
4	Catalyst-Free Intramolecular Formal Carbon Insertion into sigma-C-C Bonds: A New Approach toward Phenanthrols and Naphthols	期刊論文	Xia, Ying\|Qu, Peiyuan\|Liu, Zhenxing\|Ge, Rui\|Xiao, Qing\|Zhang, Yan\|Wang, Jianbo\|
5	Diazo Compounds and N-Tosylhydrazones: Novel Cross-Coupling Partners in Transition-Metal-Catalyzed Reactions	期刊論文	Xiao, Qing\|Zhang, Yan\|Wang, Jianbo\|
6	Rhodium(II)-Catalyzed Cyclization of Bis(N-tosylhydrazone)s: An Efficient Approach towards Polycyclic Aromatic Compounds	期刊論文	Xia, Ying\|Liu, Zhenxing\|Xiao, Qing\|Qu, Peiyuan\|Ge, Rui\|Zhang, Yan\|Wang, Jianbo\|
7	Catalytic Cascade Reactions Involving Metal Carbene Migratory Insertion	期刊論文	1. Ying Xia, Yan Zhang, Jianbo Wang*\|
8	C(sp)-C(sp(3)) Bond Formation through Cu-Catalyzed Cross-Coupling of N-Tosylhydrazones and Trialkylsilylethynes	期刊論文	Ye, Fei\|Ma, Xiaoshen\|Xiao, Qing\|Li, Huan\|Zhang, Yan\|Wang, Jianbo\|
9	硫葉立德[2,3]-σ重排反應遷移基團活性研究	期刊論文	李玉葉\|黃重行\|許鵬飛\|張艷\|王劍波\|Li,Yuyea,b Huang,Zhongxinga Xu,Peng-Feib Zhang,Yan\|
10	Palladium-Catalyzed Diarylmethyl C(sp(3))-C(sp(2)) Bond Formation: A New Coupling Approach toward Triarylmethanes	期刊論文	Xia, Ying\|Hu, Fangdong\|Liu, Zhenxing\|Qu, Peiyuan\|Ge, Rui\|Ma, Chen\|Zhang, Yan\|Wang, Jianbo\|
11	Synthesis of Aryl Trimethylstannanes from Aryl Amines: A Sandmeyer-Type Stannylation Reaction	期刊論文	王劍波\|
12	Copper-catalyzed cascade coupling/cyclization of terminal alkynes with diazoacetates: a straightforward route for trisubstituted furans	期刊論文	Zhou, Lei\|Ma, Jiachen\|Zhang, Yan\|Wang, Jianbo\|
13	New Developments in Aromatic Halogenation, Borylation, and Cyanation	期刊論文	Qiu, Di\|Mo, Fanyang\|Zheng, Zhitong\|Zhang, Yan\|Wang, Jianbo\|
14	Copper-Catalyzed Direct Ortho-Alkylation of N-Iminopyridinium Ylides with N-Tosylhydrazones	期刊論文	Xiao, Qing\|Ling, Lin\|Ye, Fei\|Tan, Renchang\|Tian, Leiming\|Zhang, Yan\|Li, Yuxue\|Wang, Jianbo\|
15	Cross-Coupling Reactions Involving Metal Carbene: From C=C/C-C Bond Formation to C-H Bond Functionalization	期刊論文	4. Zhenxing Liu\|Jianbo Wang*\|
16	Copper-Catalyzed Direct C-H Trifluoromethylation of Quinones	期刊論文	Wang, Xi\|Ye, Yuxuan\|Ji, Guojing\|Xu, Yan\|Zhang, Songnan\|Feng, Jiajie\|Zhang, Yan\|Wang, Jianbo\|
17	N-Tosylhydrazine-mediated deoxygenative hydrogenation of aldehydes and ketones catalyzed by Pd/C	期刊論文	Zhou, Lei\|Liu, Zhenxing\|Liu, Yizhou\|Zhang, Yan\|Wang, Jianbo\|
18	Cyclopropylmethyl Palladium Species from Carbene Migratory Insertion: New Routes to 1,3-Butadienes	期刊論文	Zhou, Lei\|Ye, Fei\|Zhang, Yan\|Wang, Jianbo\|
19	Reaction of Diazo Compounds with Organoboron Compounds	期刊論文	Huan Li, Yan Zhang, Jianbo Wang*\|
20	Pd-Catalyzed Carbonylation of Diazo Compounds at Atmospheric Pressure: A Catalytic Approach to Ketenes	期刊論文	Zhang, Zhenhua\|Liu, Yiyang\|Ling, Lin\|Li, Yuxue\|Dong, Yian\|Gong, Mingxing\|Zhao, Xiaokun\|Zhang, Yan\|Wang, Jianbo\|
21	Carbonylation of Metal Carbene with Carbon Monoxide: Generation of Ketene	期刊論文	Zhang, Zhenhua\|Zhang, Yan\|Wang, Jianbo\|
22	Studies Toward the Synthesis of (R)-(+)-Harmicine	期刊論文	Fanyang Mo\|Fei Li\|Di Qiu\|Yan Zhang\|Jianbo Wang\|
23	Lewis Acid Catalyzed Direct Cyanation of Indoles and Pyrroles with N-Cyano-N-phenyl-p-toluenesulfonamide (NCTS)	期刊論文	Yang, Yang\|Zhang, Yan\|Wang, Jianbo\|
24	Transition-Metal-Free Electrophilic Amination of Arylboroxines	期刊論文	Xiao, Qing\|Tian, Leiming\|Tan, Renchang\|Xia, Ying\|Qiu, Di\|Zhang, Yan\|Wang, Jianbo\|
25	Pd-catalyzed coupling of beta-hydroxy alpha-diazocarbonyl compounds with aryl iodides: a migratory insertion/beta-hydroxy elimination sequence	期刊論文	Zhou, Lei\|Liu, Yizhou\|Zhang, Yan\|Wang, Jianbo\|
26	Pd-Catalyzed Cyclization and Carbene Migratory Insertion: New Approach to 3-Vinylindoles and 3-Vinylbenzofurans	期刊論文	3. Zhenxing Liu, Ying Xia, Shiyi Zhou, Long Wang,\|
27	Catalytic Thia-Sommelet-Hauser Rearrangement: Application to the Synthesis of Oxindoles	期刊論文	Li, Yuye\|Shi, Yi\|Huang, Zhongxing\|Wu, Xinhu\|Xu, Pengfei\|Wang, Jianbo\|Zhang, Yan\|
28	Recent Developments in Pd-Catalyzed Reactions of Diazo Compounds	期刊論文	Zhang, Yan\|Wang, Jianbo\|
29	Palladium-Catalyzed Oxidative Cross-Coupling of N-Tosylhydrazones or Diazoesters with Terminal Alkynes: A Route to Conjugated Enynes	期刊論文	Zhou, Lei\|Ye, Fei\|Ma, Jiachen\|Zhang, Yan\|Wang, Jianbo\|
30	Rh(II)-catalyzed [2,3]-sigmatropic rearrangement of sulfur ylides derived from N-tosylhydrazones and sulfides	期刊論文	Li, Yuye\|Huang, Zhongxing\|Wu, Xinhu\|Xu, Peng-Fei\|Jin, Jing\|Zhang, Yan\|Wang, Jianbo\|
31	Transition-Metal-Catalyzed Cross-Coupling Reaction with N-Tosylhydrazones	期刊論文	Liu Zhenxing\|Zhang Yan\|Wang Jianbo\|
32	Sequential Au(I)-catalyzed reaction of water with o-acetylenyl-substituted phenyldiazoacetates	期刊論文	Zhou, Lei\|Liu, Yizhou\|Zhang, Yan\|Wang, Jianbo\|
33	Synthesis of Allyl Allenes through Three-Component Cross-Coupling Reaction of N-Tosylhydrazones, Terminal Alkynes, and Allyl Halides	期刊論文	Ye, Fei\|Hossain, Mohammad Lokman\|Xu, Yan\|Ma, Xiaoshen\|Xiao, Qing\|Zhang, Yan\|Wang, Jianbo\|
34	Increments for H-1 and C-13 NMR chemical shifts in pinacol arylboronates	期刊論文	Qiu, Di\|Zheng, Zhitong\|Mo, Fanyang\|Zhang, Yan\|Wang, Jianbo\|
35	Pd-Catalyzed Three-Component Reaction of Allenes, Aryl Iodides and Diazo Compounds: New Approach to 1,3-Dienes	期刊論文	Qing Xiao, Binglong Wang, Leiming Tian, Yang Yang\|
36	Synthesis of Aryltrimethylstannanes from Arylamines: A Sandmeyer-Type Stannylation Reaction	期刊論文	Di Qiu, He Meng, Liang Jin, Shuai Wang, Shengbo T\|
37	Catalyst-Free Imidation of Allyl Sulfides with Chloramine-T and Subsequent [2,3]-Sigmatropic Rearrangement	期刊論文	Jiang Yubo\|Mo Fanyang\|Qiu Di\|Kuang Chunxiang\|Zhang Yan\|Wang Jianbo\|
38	Palladium-catalyzed Cross-coupling of Aryl Iodides with beta-Trimethylsiloxy-alpha-diazoesters: A Novel Approach toward beta-Keto-alpha-arylesters	期刊論文	Shu, Zhibin\|Zhang, Ji\|Zhang, Yan\|Wang, Jianbo\|
39	Coupling of N-Tosylhydrazones with Terminal Alkynes Catalyzed by Copper(I): Synthesis of Trisubstituted Allenes	期刊論文	Xiao, Qing\|Xia, Ying\|Li, Huan\|Zhang, Yan\|Wang, Jianbo\|
40	Recent developments in copper-catalyzed reactions of diazo compounds	期刊論文	Zhao, Xia\|Zhang, Yan\|Wang, Jianbo\|
41	Recent applications of arene diazonium salts in organic synthesis	期刊論文	Mo, Fanyang\|Dong, Guangbin\|Zhang, Yan\|Wang, Jianbo\|
42	Synthesis of Pinacol Arylboronates from Aromatic Amines: A Metal-Free Transformation	期刊論文	Qiu, Di\|Jin, Liang\|Zheng, Zhitong\|Meng, He\|Mo, Fanyang\|Wang, Xi\|Zhang, Yan\|Wang, Jianbo\|
43	CuI-Catalyzed Cross-Coupling of N-Tosylhydrazones with Terminal Alkynes: Synthesis of 1,3-Disubstituted Allenes	期刊論文	Hossain, Mohammad Lokman\|Ye, Fei\|Zhang, Yan\|Wang, Jianbo\|
44	經由三氟甲基自由基的三氟甲基化反應研究進展	期刊論文	王兮\|張艷\|王劍波\|WANG Xi,ZHANG Yan,WANG JianBo* Key Laboratory of B\|Beijing National Laboratory for Molecular Sciences\|College of Chemistry and Molecular Engineering,Pek\|
45	Palladium(II)-Catalyzed Direct Conversion of Methyl Arenes into Aromatic Nitriles	期刊論文	Shu, Zhibin\|Ye, Yuxuan\|Deng, Yifan\|Zhang, Yan\|Wang, Jianbo\|
46	Expeditious Synthesis of Phenanthrenes via CuBr(2)-Catalyzed Coupling of Terminal Alkynes and N-Tosylhydrazones Derived from O-Formyl Biphenyls	期刊論文	Ye, Fei\|Shi, Yi\|Zhou, Lei\|Xiao, Qing\|Zhang, Yan\|Wang, Jianbo\|
47	Transition-Metal-Free Synthesis of Pinacol Alkylboronates from Tosylhydrazones	期刊論文	Li, Huan\|Wang, Long\|Zhang, Yan\|Wang, Jianbo\|
48	Silver-Mediated Trifluoromethylation of Aryldiazonium Salts: Conversion of Amino Group into Trifluoromethyl Group	期刊論文	Wang, Jianbo\|Xu, Yan\|Mo, Fanyang\|Ji, Guojing\|Qiu, Di\|Feng, Jiajie\|Ye, Yuxuan\|Zhang, Songnan\|Zhang, Yan\|
49	Auto-Tandem Catalysis: Synthesis of Acridines by Pd-Catalyzed C=C Bond Formation and C(sp2)-N Cross-Coupling	期刊論文	Zhongxing Huang\|Yang Yang\|Qing Xiao\|Yan Zhang\|Jianbo Wang*\|
50	Copper-Catalyzed C(sp(3))-C(sp(3)) Bond Formation Using a Hypervalent Iodine Reagent: An Efficient Allylic Trifluoromethylation	期刊論文	Wang, Xi\|Ye, Yuxuan\|Zhang, Songnan\|Feng, Jiajie\|Xu, Yan\|Zhang, Yan\|Wang, Jianbo\|
51	A base-free, one-pot diazotization/cross-coupling of anilines with arylboronic acids	期刊論文	Mo, Fanyang\|Qiu, Di\|Jiang, Yubo\|Zhang, Yan\|Wang, Jianbo\|
52	Ru(II)-Catalyzed rearrangement of 2-aryl-2-(phenylthio)penta-3,4-dienyl 2,2,2-trichloroacetimidates	期刊論文	Peng, Lingling\|Zhang, Xiu\|Ma, Jie\|Wang, Jianbo\|
53	Copper-Catalyzed Direct Benzylation or Allylation of 1,3-Azoles with N-Tosylhydrazones	期刊論文	Zhao, Xia\|Wu, Guojiao\|Zhang, Yan\|Wang, Jianbo\|

項目摘要

鈀卡賓經由的催化反應具有和傳統的鈀催化反應不同的反應特性，鈀卡賓自身也和其它金屬卡賓的反應性不同，因此近年來這方面的研究引起人們的關注。鈀卡賓的一個特徵反應是發生轉移插入，形成碳鈀單鍵物種。本項研究是進一步拓展鈀卡賓轉移插入反應的範圍，並將這類反應套用於串聯反應構建結構複雜的有機化合物，發展鈀催化反應的新方法學。

以鈀卡賓為基礎的催化反應研究

基本介紹

科研成果

項目摘要

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